Amino-functionalized magnetic nanoparticles for CO<sub>2</sub> capture

نویسندگان

چکیده

CO2 accumulation is inducing an effect of global warming. Adsorption using solid sorbents proving as effective strategy for capture and reuse. The aim this study was to develop amino-functionalized magnetic nanoparticles by depositing various amines through co-precipitation or impregnation-sonication. Structural characteristics were studied SEM, BET XRD analyses, evidencing coarse particles with low crystallinity surface areas 100–150 m2 g−1, while FT-IR confirmed interacting substrate. load functional group, stability, sorption capacity assessed elemental thermogravimetric analysis. It found that loads groups ranging from 1.6 6.1 wt.%. deposited, most samples showed sound stability up 100°C. Sorption capacities in the range 0.2–1.5 g gNH2−1, highest being 1.46 gNH2−1 ɛ-aminocaproic acid. Such sample also exhibited good recyclability, a performance drop 11% after many cycles. uptake decreased increasing temperature 25–45°C, suggesting chemical bond between amines. Amino functionalized could thus be interesting solution utilization thanks fast kinetics, ease separation.

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ژورنال

عنوان ژورنال: International Journal of Smart and Nano Materials

سال: 2021

ISSN: ['1947-542X', '1947-5411']

DOI: https://doi.org/10.1080/19475411.2021.1987350